Cl O H C P Pr dummy (HA)2(org) dodecane Pr(H(A)2)3(org) 298.15 100000.0 (HA)2(org): 0.25 C:16 H:35 O:3 P:1 298.14999999999998 -1460300.0 558.9824 0.0 0.32 C:48 H:102 O:9 P:3 Pr:1 298.14999999999998 -5177400.0 1117.965 0.0 0.94 dummy:1 298.14999999999998 0.0 0.0 0.0 0.227113 H2O(L) H+ OH- Cl- Pr+++ 298.15 100000.0 Cl-: 1.0E-7 H+: 1.0E-7 0.177000779, 0.000125778, 0.0, -33.4777082, -0.262214535 0.292922504, -0.027938838, 0.0, 3402.47027, 19.7936248 0.0, 0.0, 0.0, 0.0, 0.0 0.000362, -0.00003036, 0.0, -2.91038E-11, 0.0 2 12 refit of Holmes, H.F., Busey, J.M., Simonson, J.M., Mesmer, R.E., Archer, D.G., and Wood, R.H., 1987, The enthalpy of dilution of HCl(aq) to 648 K and 4p MPa. Thermodynamic properties, Journal of Chemical Thermodynamics, v. 19, p. 863-890. 0.123757018, 0.0, 0.0, 0.0, 0.0 0.31055417, 0.0, 0.0, 0.0, 0.0 0.0, 0.0, 0.0, 0.0, 0.0 -0.005539018, 0.0, 0.0, 0.0, 0.0 2 12 02mar (Table 3) Marion, G. M. (2002) "A molal-based model for strong acid chemistry at low temperatures (less than 200 to 298 K)", Geochimica et Cosmochimica Acta, Vol. 66, No. 14, pp. 2499-2516. These parameters are derived from the mole fraction model of Clegg and Brimblecombe (1990) but were parameterized by Marion (2002) for the Pitzer molality-based model. 0.5879, 0.0, 0.0, 0.0, 0.0 5.4479999999999995, 0.0, 0.0, 0.0, 0.0 0.0, 0.0, 0.0, 0.0, 0.0 -0.020669999999999997, 0.0, 0.0, 0.0, 0.0 2 0 Table S1: Pitzer parameters for osmotic and activity coeff Supp Info. May, P. M.; Rowland, D.; Hefter, G.; Konigsberger, E. A generic and updatable Pitzer characterization of aqueous binary electrolyte solutions at 1 bar and 25 C. Journal of Chemical and Engineering Data 2011,56, 5066–5077. H2O(L) O H Pr C Fe Si N Na Cl Ca P E H:2 O:1 7.255750050E+01, -6.624454020E-01, 2.561987460E-03, -4.365919230E-06, 2.781789810E-09, -4.188654990E+04, -2.882801370E+02 0.018068 OH- O:1 H:1 -1 -37595 -54977 -2.56 0.12527 7.38 1.8423 -27821 4.15 -103460 172460 ref:G9 NO3- N:1 O:3 -1 -26507 -49429 35.12 0.73161 678.24 -4.6838 -30594 7.7 -67250 109770 ref:G9 Na+ Na:1 1 -62591 -57433 13.96 0.1839 -228.5 3.256 -27260 18.18 -29810 33060 ref:G9 Cl- Cl:1 -1 -31379 -39933 13.56 0.4032 480.1 5.563 -28470 -4.4 -57140 145600 17.79 ref:G9 H+ H:1 +1 0 0 0 0 0 0 0 0 0 0 0 ref:G9 Pr+++ Pr:1 +3 -162600 -168800 -50 -0.32406 -1419.98 8.1257 -21920 -1.1975 -127511 223500 -42.1 ref:G9